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- W2056574725 abstract "The kinetics of the etherification of tert-amyl alcohol with ethanol, catalysed by a strong ion-exchange resin, Amberlyst 15, has been studied in a batch reactor at temperatures between 323 and 353K and at a pressure of 0.8MPa. The kinetics was described by a coupled sorption–reaction model. Flory–Huggins (F–H) model was used to predict the solubility of reaction components in the resin phase at 278K (non-reactive conditions). Both sorption interaction parameters of F–H model and kinetic constants were determined by non-linear least-squares method. Langmuir–Hinshelwood (L–H) and power law (PL) kinetic models were compared with the experimental data. Although both the models were found to be equally successful, L–H model has shown a slightly better representation than PL model." @default.
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- W2056574725 date "2003-05-01" @default.
- W2056574725 modified "2023-09-29" @default.
- W2056574725 title "Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol" @default.
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- W2056574725 doi "https://doi.org/10.1016/s0009-2509(03)00052-6" @default.
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