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- W2056574991 abstract "Differential scanning calorimetry (d.s.c.) and water vapour pressure measurement have been used to investigate the poly(ethylene glycol) (PEG) interaction with water. There is a clear evidence for the existence of stable crystalline complexes. One complex clearly contains three moles of water per ether group and exists even at a concentration of 1 part by weight of PEG in 17 parts of water. It melts below p°C. The vapour pressure results indicate a lower hydrate, which could be a monohydrate, but the evidence from the d.s.c. analysis for this hydrate is less definitive. The formation and stability of these hydrates as a function of molecular weight is further discussed relative to ΔHfus and ΔSfus values determined from d.s.c. curves." @default.
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- W2056574991 date "1989-03-01" @default.
- W2056574991 modified "2023-10-11" @default.
- W2056574991 title "Interaction of poly(ethylene oxide) with solvents: 2. Water-poly(ethylene glycol)" @default.
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- W2056574991 doi "https://doi.org/10.1016/0032-3861(89)90026-8" @default.
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