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- W2056575162 abstract "It was found that γ-radiolysis of n-alkanes (Cn=6–8) and cyclohexane in CFCl2CF2Cl and CF3CCl3 in the liquid phase produces corresponding monochlorinated alkanes with a high G-values (⩾ 600). This chlorination occured selectively at the positions C2 and C3, and the yield of 1-chlorohexane was <4% of the sum of the former. The selective hydrogenation of CFCl2CF2Cl was also found with a yield as high as that of the chlorination of the alkanes. The role of positive charge transfer from the solvent to the alkane with a high G-value, and that of the bond energy difference between the primary and secondary C—H bonds in the selective chlorination and hydrogenation are suggested." @default.
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- W2056575162 date "1990-01-01" @default.
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- W2056575162 title "Selective chlorination of alkanes and hydrogenation of chloroflouroethane with high g-values in the radiolysis of their liquid mixture: High resolution NMR study" @default.
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- W2056575162 doi "https://doi.org/10.1016/1359-0197(90)90031-c" @default.
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