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• W2056576603 abstract "The fluorescence of both cyclohexane and benzene in their irradiated mixtures has been studied as a function of benzene concentration from ∼ 0.005 to 0.1 M. The quenchi by benzene is found to be significantly greater than obtained under optical excitation conditions suggesting an important role for benzene as a scavenger of the geminate ion-pair precursor of the fluorescing state of cyclohexane. From diffusion models, a lower bound is established for the scavenging rate constant. An examination of the fluorescence from benzene leads to the conclusion that although the majority of benzene fluorescence drives from electronic energy transfer from excited cyclohexane, a large fraction (from 20 to 50% over the concentration range studied) is generated by recombining molecular ions. The intrinsic efficiency with which the recombining ions generate fluorescent states of benzene, however, appears to be peculiarly low." @default.
• W2056576603 created "2016-06-24" @default.
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• W2056576603 date "1991-01-01" @default.
• W2056576603 modified "2023-10-05" @default.
• W2056576603 title "Energy transfer from cyclohexane to benzene in their irradiated mixtures" @default.
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• W2056576603 doi "https://doi.org/10.1016/1359-0197(91)90044-3" @default.
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