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- W2056577066 abstract "The 8S72 ground state splittings of [xGd, (1 − x)La]·(C2H5SO4)3·9H2O where x = 0.005, 0.01, 0.02 have been determined by linear extrapolation from measurements in 1.5–6.0 mT magnetic fields to an accuracy of ≈ ± 0.3 MHz using weak magnetic field variable frequency EPR at 290.5 and 77 K. An anomalous splitting of the 8S72 ground state ∥±12> doublet in zero magnetic field is inferred, which is found to be concentration- and temperature-dependent. This splitting is determined to be (16.0 ± 0.5) MHz at 290.5 K and (10.3 ± 1.0) MHz at 77 K for 0.5 % Gd concentration, whereas the ∥±32>, ∥±52> and ∥±72> doublets remain degenerate in zero magnetic field within present experimental accuracy. The unique features of a weak magnetic field variable frequency EPR spectrometer are described." @default.
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- W2056577066 date "1976-02-01" @default.
- W2056577066 modified "2023-09-27" @default.
- W2056577066 title "Anomalous splitting of the ground state of gadolinium ion in lanthanum ethyl sulfate" @default.
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- W2056577066 doi "https://doi.org/10.1016/0022-2364(76)90077-9" @default.
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