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- W2056578272 abstract "Orientations of three rigid diphenylpolyene probes of different lengths (1.15, 1.4 and 1.65 nm) in uniaxially deformed cis-1,4-polyisoprene networks are determined by fluorescence polarization measurements. The degree of coupling between the probes and the network is explained by a theoretical model, leading to the expression f = f0 + f2S2, where f0 and f show the degree of coupling in the undeformed and deformed networks, respectively, f2 is a coefficient to be determined experimentally and S is the orientation function for the network. The degree of coupling of the probes to the network chains varied inversely with probe lengths but was independent of temperature changes and the degree of swelling. A likely molecular origin of the coupling of polyisoprene chains with the probes would involve the statistically favourable skew±,trans,skew∓ sequences." @default.
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- W2056578272 date "1987-04-01" @default.
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- W2056578272 title "Orientation of rigid rods dissolved in deformed networks" @default.
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- W2056578272 doi "https://doi.org/10.1016/0032-3861(87)90220-5" @default.
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