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- W2056578669 abstract "Nonstoichiometry of (Mg0.22Mn0.07Fe0.71)3−δO4 ferrite has been measured in the temperature range of 1000×1200°C as a function of oxygen activity (aO2) using a solid state coulometric titration technique. At a given temperature, the nonstoichiometry (δ) was found to vary with the oxygen activity as δ=[V]0 · a2/3O2 −[I]0·a−2/3O2 where [V]0 and [I]0 are constants. This aO2-dependence of δ was explained in terms of Frenkel disorder, i.e., cation vacancy and interstitial. From the temperature dependence of the defect constants ([V]0 and [I]0) and the oxygen activity for the stoichiometric composition (δ=0), thermodynamic quantities such as enthalpies for the defect formation reactions and relative partial molar enthalpy and entropy of oxygen were calculated." @default.
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- W2056578669 date "1999-06-01" @default.
- W2056578669 modified "2023-10-18" @default.
- W2056578669 title "Nonstoichiometry (δ) and High-Temperature Thermodynamic Properties of (Mg0.22Mn0.07Fe0.71)3−O4 Ferrite Spinel" @default.
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- W2056578669 doi "https://doi.org/10.1006/jssc.1999.8264" @default.
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