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- W2056578710 abstract "Cloud-point curves for solutions of five polystyrene samples, including three well-fractionated polystyrenes, in cyclohexane have been examined near their critical points. Even for a solution of polystyrene characterized by MwMn<1.03, the critical point determined by the phase-volume method is generally situated on the right hand branch of the cloud-point curve. The precipitation threshold concentration is appreciably lower than the critical concentration, while the threshold temperature slightly deviates from the critical temperature. The agreement of the precipitation threshold point with the critical point has been found for a solution of polystyrene characterized by Mw=20×104 and MwMn<1.02 in cyclohexane. The η(φ) function derived from critical miscibility data is expressed by χ(φ) = 0.2798+67.50T+0.3070φ+0.2589φ2, which yields θ of 33.2°C and ψ1 of 0.22." @default.
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- W2056578710 date "1973-09-01" @default.
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- W2056578710 title "Cloud-point curves of the polystyrene-cyclohexane system near the critical point" @default.
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- W2056578710 doi "https://doi.org/10.1016/0032-3861(73)90005-0" @default.
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