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- W2056584365 abstract "Far infrared spectra (700∼40 cm−1) of ethyl methyl ether and deuterated species (CH3CH2OCD3, CD3CH2OCH3, CH3CD2OCH3, and CD3CD2OCH3) were measured in the crystalline, liquid and gaseous states and carbon tetrachloride solution. A low temperature cell was constructed for measuring far infrared absorption of highly volatile samples in the liquid and crystalline states. Far infrared bands due to skeletal bending vibrations of the trans and gauche isomers and lattice vibrations were assigned. From analyses of isotope effects on infrared frequencies, internal-rotation vibrations of the CH3-CH2, CH2-O, and O-CH3 bonds of the trans isomer of ethyl methyl ether were found at 248, 115, and 202 cm−1, respectively, in the gaseous state. Normal vibrations were treated with the local-symmetry force field and force constants were adjusted by the method of least squares. By the use of Mathieu equation, the threefold potential barriers of the methyl groups of the trans isomer were estimated as V3(CH3-C)=3.3±0.1 and V3(O-CH3)=2.5±0.1 kcal/mol." @default.
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- W2056584365 date "1972-04-01" @default.
- W2056584365 modified "2023-10-16" @default.
- W2056584365 title "Far Infrared Spectra and Internal-Rotation Potential of Ethyl Methyl Ether" @default.
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- W2056584365 doi "https://doi.org/10.1246/bcsj.45.969" @default.
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