Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056588683> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2056588683 endingPage "2466" @default.
- W2056588683 startingPage "2461" @default.
- W2056588683 abstract "The syntheses of a new nitroxide bearing a sulfoxide group at the β-position (with respect to nitrogen) and the corresponding N-β-sulfinyl alkoxyamine are reported. Styrene was polymerized in bulk in the presence of this new alkoxyamine. The polymerization satisfies the usual criteria of a living/controlled radical polymerization, with a linear increase of molecular weight vs yield and a constant transient radical concentration with time. However, the polymerization rates were independent of alkoxyamine concentration but much higher than the thermal polymerization ones: Rp/Rth = 2.6 at 90 °C, 3.7 at 100 °C, and 3.5 at 110 °C. Kinetic and ESR studies showed that both transient and persistent radical concentrations do not follow the corresponding theoretical evolutions with time but reach stationary states. The different rate constants (kd and kc) and corresponding activation energies were estimated, showing that the sulfoxide group has a large effect mainly on the combination reaction, the value of which is unusually low for such system (kc ≈ 105 L mol-1 s-1)." @default.
- W2056588683 created "2016-06-24" @default.
- W2056588683 creator A5063425176 @default.
- W2056588683 creator A5067366062 @default.
- W2056588683 date "2002-02-22" @default.
- W2056588683 modified "2023-09-25" @default.
- W2056588683 title "Synthesis of a New Stable β-Sulfinyl Nitroxide and the Corresponding Alkoxyamine for Living/Controlled Radical Polymerization of Styrene: Kinetic and ESR Studies" @default.
- W2056588683 cites W1971674116 @default.
- W2056588683 cites W1973637914 @default.
- W2056588683 cites W1980559714 @default.
- W2056588683 cites W1993758718 @default.
- W2056588683 cites W1993808007 @default.
- W2056588683 cites W1996673306 @default.
- W2056588683 cites W2007252860 @default.
- W2056588683 cites W2009588904 @default.
- W2056588683 cites W2022560849 @default.
- W2056588683 cites W2036707632 @default.
- W2056588683 cites W2052304852 @default.
- W2056588683 cites W2068728922 @default.
- W2056588683 cites W2077235613 @default.
- W2056588683 cites W2080071613 @default.
- W2056588683 cites W2093493056 @default.
- W2056588683 cites W2121893149 @default.
- W2056588683 cites W2144122182 @default.
- W2056588683 cites W2153925194 @default.
- W2056588683 cites W2320094026 @default.
- W2056588683 cites W2333852227 @default.
- W2056588683 cites W4256667536 @default.
- W2056588683 doi "https://doi.org/10.1021/ma011063k" @default.
- W2056588683 hasPublicationYear "2002" @default.
- W2056588683 type Work @default.
- W2056588683 sameAs 2056588683 @default.
- W2056588683 citedByCount "55" @default.
- W2056588683 countsByYear W20565886832012 @default.
- W2056588683 countsByYear W20565886832013 @default.
- W2056588683 countsByYear W20565886832014 @default.
- W2056588683 countsByYear W20565886832015 @default.
- W2056588683 countsByYear W20565886832016 @default.
- W2056588683 countsByYear W20565886832020 @default.
- W2056588683 countsByYear W20565886832022 @default.
- W2056588683 crossrefType "journal-article" @default.
- W2056588683 hasAuthorship W2056588683A5063425176 @default.
- W2056588683 hasAuthorship W2056588683A5067366062 @default.
- W2056588683 hasConcept C111998727 @default.
- W2056588683 hasConcept C121332964 @default.
- W2056588683 hasConcept C148898269 @default.
- W2056588683 hasConcept C15920480 @default.
- W2056588683 hasConcept C169912494 @default.
- W2056588683 hasConcept C178790620 @default.
- W2056588683 hasConcept C185592680 @default.
- W2056588683 hasConcept C188027245 @default.
- W2056588683 hasConcept C2777566558 @default.
- W2056588683 hasConcept C44228677 @default.
- W2056588683 hasConcept C521977710 @default.
- W2056588683 hasConcept C62520636 @default.
- W2056588683 hasConcept C75473681 @default.
- W2056588683 hasConcept C93391505 @default.
- W2056588683 hasConceptScore W2056588683C111998727 @default.
- W2056588683 hasConceptScore W2056588683C121332964 @default.
- W2056588683 hasConceptScore W2056588683C148898269 @default.
- W2056588683 hasConceptScore W2056588683C15920480 @default.
- W2056588683 hasConceptScore W2056588683C169912494 @default.
- W2056588683 hasConceptScore W2056588683C178790620 @default.
- W2056588683 hasConceptScore W2056588683C185592680 @default.
- W2056588683 hasConceptScore W2056588683C188027245 @default.
- W2056588683 hasConceptScore W2056588683C2777566558 @default.
- W2056588683 hasConceptScore W2056588683C44228677 @default.
- W2056588683 hasConceptScore W2056588683C521977710 @default.
- W2056588683 hasConceptScore W2056588683C62520636 @default.
- W2056588683 hasConceptScore W2056588683C75473681 @default.
- W2056588683 hasConceptScore W2056588683C93391505 @default.
- W2056588683 hasIssue "7" @default.
- W2056588683 hasLocation W20565886831 @default.
- W2056588683 hasOpenAccess W2056588683 @default.
- W2056588683 hasPrimaryLocation W20565886831 @default.
- W2056588683 hasRelatedWork W2002790351 @default.
- W2056588683 hasRelatedWork W2019392154 @default.
- W2056588683 hasRelatedWork W2019953135 @default.
- W2056588683 hasRelatedWork W2025980868 @default.
- W2056588683 hasRelatedWork W2040256472 @default.
- W2056588683 hasRelatedWork W2049671541 @default.
- W2056588683 hasRelatedWork W2061681622 @default.
- W2056588683 hasRelatedWork W2068216468 @default.
- W2056588683 hasRelatedWork W2068419867 @default.
- W2056588683 hasRelatedWork W2327386358 @default.
- W2056588683 hasVolume "35" @default.
- W2056588683 isParatext "false" @default.
- W2056588683 isRetracted "false" @default.
- W2056588683 magId "2056588683" @default.
- W2056588683 workType "article" @default.