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- W2056590061 abstract "Abstract The thermal analysis of the complexes [Ni(phen) 3 ][PdCl 4 ]·3H 2 O and [Ni(bipy) 3 ][PdCl 4 ]·2 1 2 –H 2 O revealed, after the elimination of the molecules of water, the reciprocal migration of the ligands between the coordination spheres of the two metal ions. This solid-state reaction leads to mixtures of two neutral complexes: Ni(AA) 2 Cl 2 and Pd(AA)Cl 2 (AA=phenanthroline or bipyridine). In both cases, the migration was found to be exothermic. The bis-chelated nickel complexes, Ni(AA) 2 Cl 2 , were extracted in ethanol and separated from Pd(AA)Cl 2 . Subsequent addition of an hydrochloric acid solution of ZnCl 2 to the ethanol solution containing Ni(phen) 2 Cl 2 led to the formation of [Ni(phen) 2 (H 2 O) 2 ][ZnCl 4 ]·H 2 O which was studied by X-ray diffraction methods. The Ni–N bond distances vary from 2.078(3) to 2.089(4)A, while the cis Ni–O distances are 2.057(3) and 2.073(3) A. The crystal structure of Ni(bipy) 2 Cl 2 ·2H 2 O· 1 2 –CH 3 CN was also determined. The compound is the cis isomer, with the Ni atom located on a 2-fold axis. The Ni–N bonds distances are 2.084(3) and 2.094(2) A, while the Ni–Cl bonds distances are 2.428(1) A. The compound crystallizes with two water molecules situated in the lattice and 1 2 – molecule of acetonitrile located on a 2-fold axis. The two crystals are stabilized by hydrogen bonds involving the water molecules." @default.
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- W2056590061 date "1998-10-01" @default.
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- W2056590061 title "Solid-state chemistry of [Ni(AA)3][PdCl4] · nH2O complexes (AA=bipy, phen) and crystal structures of cis-diaqua-bis(phenanthroline)nickel(II) tetrachlorozincate and cis-dichloro-bis(bipyridine)nickel(II)" @default.
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- W2056590061 doi "https://doi.org/10.1016/s0277-5387(98)00128-4" @default.
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