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- W2056593708 endingPage "518" @default.
- W2056593708 startingPage "512" @default.
- W2056593708 abstract "Abstract The hydrothermal reactions of a cobalt(II) salt and 5-(4-pyridyl)tetrazole in the presence of phosphate provided two three-dimensional materials of the M(II)/azolate/anion family [Co3(4-pt)3(PO4)] (1) and [Co3(H2O)4(4-pt)2(HOPO3)2] (2) (M(II) = Co; azolate = 5-(4-pyridyl)tetrazole or 4-Hpt; and anion = PO43− (1) and HPO42− (2)). The structures are characterized by the incorporation of metal cluster secondary building units (SBU). The structure of 1 features a variant of the common {M3(μ3-O)} sbu with the central bridging ligand provided by a phosphate oxygen rather than the more common oxo- or hydroxy-ligand. These trinuclear units are bridged through the remaining phosphate oxygen donors into chains which are in turn linked through the pyridyltetrazolate ligands into the framework structure. In the case of compound 2, {Co3(H2O)4}6+ linear trinuclear secondary building units are linked to four adjacent clusters through {HOPO3}2− tetrahedra to generate cobalt(II)-hydrogen phosphate layers, which are linked through the 4-pt ligands into the overall framework." @default.
- W2056593708 created "2016-06-24" @default.
- W2056593708 creator A5066915870 @default.
- W2056593708 creator A5076995372 @default.
- W2056593708 date "2013-01-01" @default.
- W2056593708 modified "2023-09-24" @default.
- W2056593708 title "Solid state coordination chemistry of metal-azolate compounds: Structural consequences of incorporation of phosphate components in the Co(II)/4-pyridyltetrazolate/phosphate system" @default.
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