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- W2056598349 abstract "Fifty-seven samples have been analyzed with regard to the occurrence of dimeric procyanidins B1−B8 as well as the composition of polymeric procyanidins. Fifty-two samples were found to contain polymeric procyanidins. In most of the samples, (−)-epicatechin was the predominant unit present. In white willow bark (Salix alba), however, large amounts of (+)-catechin (81.0%) were determined by means of phloroglucinolysis. White willow bark has therefore been used for the semisynthetic formation of dimeric procyanidins B3 [(+)-C-4α → 8-(+)-C)], B4 [(+)-C-4α → 8-(−)-EC)], B6 [(+)-C-4α → 6-(+)-C)], and B8 [(+)-C-4α → 6-(−)-EC)]. The reaction mixtures of the semisynthesis were successfully fractionated with high-speed countercurrent chromatography (HSCCC), and dimeric procyanidins B3, B4, B6, and B8 were obtained on a preparative scale." @default.
- W2056598349 created "2016-06-24" @default.
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- W2056598349 date "2010-06-09" @default.
- W2056598349 modified "2023-09-27" @default.
- W2056598349 title "Dimeric Procyanidins: Screening for B1 to B8 and Semisynthetic Preparation of B3, B4, B6, and B8 from a Polymeric Procyanidin Fraction of White Willow Bark (<i>Salix alba</i>)" @default.
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- W2056598349 doi "https://doi.org/10.1021/jf101023e" @default.
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