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- W2056608939 abstract "In n-hexane matrices, at 77 K, the phosphorescence spectra of 1,9-, 1,8-, 1,7- and 4,7- phenanthrolines show quasi-linear structure (Shpolskii effect). Highly resolved spectra of isometric phenanthrolines allow measuring slight differences between 0-0 wave numbers of respective isomers and detecting characteristic features of the vibronic structure of the spectrum of each isomer. Vibrational analysis of the spectra show that in T1 → S0 electronic transitions of the phenanthrolines examined there participates, besides the totally symmetric ones, at least one out-of-plane vibration (a2 or a″). The presence of this vibration and its combination with the totally symmetric ones seem to explain the shape of phosphorescence polarization spectra of phenanthrolines in polar glasses, described in the literature." @default.
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- W2056608939 date "1978-09-01" @default.
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- W2056608939 title "Highly resolved electronic absorption and luminescence spectra of some phenanthrolines in Shpolskii matrices part I. Phosphorescence spectra" @default.
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- W2056608939 doi "https://doi.org/10.1016/0022-2313(78)90061-3" @default.
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