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• W2056629593 abstract "Using time-resolved photoluminescence and excited-state absorption spectroscopy, we investigate the chain length dependence of the energies of the singlet (S1) and triplet (T1 and Tn) excited states of a homologous series of conjugated 9,9-dihexylfluorene-2,7-diyl oligomers (nF, n = 1, 3, 5, 7, ∼50) in frozen solution. The energies of the optical transitions in absorption, fluorescence, phosphorescence, and triplet–triplet absorption initially decrease linearly with the reciprocal number of repeat units, but saturate at n⩾5. The saturation and dispersion of the optical transition energies indicate that the T1 state is only slightly more confined than the S1 state." @default.
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• W2056629593 date "2005-08-01" @default.
• W2056629593 modified "2023-10-10" @default.
• W2056629593 title "Comparison of the chain length dependence of the singlet- and triplet-excited states of oligofluorenes" @default.
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• W2056629593 doi "https://doi.org/10.1016/j.cplett.2005.06.039" @default.
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