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- W2056645346 abstract "The absolute ultraviolet absorption cross sections of methyl mercaptan (CH3SH) have been determined in the wavelength region 192.5–309.5 nm at 296 K. The uv absorbance, A, in a column of slowly flowing standard CH3SH/helium gas mixtures, was monitored in long Pyrex absorption cells of path length, l, at several different pressures at the ambient cell temperature using a diode-array spectrometer with an instrumental resolution ranging from 0.25 to 1.10 nm. The absorption cross sections, σ=A/l[CH3SH], were calculated using the Beer–Lambert law from the known partial pressure of CH3SH in the gas mixture. The primary quantum yields of H atom produced in the 222 and 193 nm laser photolysis of CH3SH have been determined to be 0.95±0.10 and 0.49±0.08 relative to 248 nm CH3SH photolysis and 193 nm HBr photolysis, respectively, at 296 K. The H atoms were directly monitored in the photolysis by resonance fluorescence detection of H(2S)." @default.
- W2056645346 created "2016-06-24" @default.
- W2056645346 creator A5012917229 @default.
- W2056645346 date "1993-10-15" @default.
- W2056645346 modified "2023-10-04" @default.
- W2056645346 title "CH3SH ultraviolet absorption cross sections in the region 192.5–309.5 nm and photodecomposition at 222 and 193 nm and 296 K" @default.
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- W2056645346 doi "https://doi.org/10.1063/1.465917" @default.
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