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- W2056680443 abstract "Activation energies of 1,12-benzperylene fluorescence quenching ( E Q ) in acetonitrile by a series of electron donors and acceptors and of radical ion ( E R ) and triplet state ( E T ) formation were determined from Arrhenius plots of the quantum yields. The quenchers were chosen in the range of Gibbs energies of electron transfer Δ G et =−100 to 6 kJ mol −1 . Surprisingly low E Q , E R and E T values were obtained when Δ G et >−5 kJ mol −1 . The effects of temperature are discussed from the point of view of two alternative mechanisms: the conventional mechanism of direct electron transfer and that of transient exciplex formation. Evidence for the latter is given." @default.
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- W2056680443 date "1998-01-01" @default.
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- W2056680443 title "Temperature effects on radical ion and triplet quantum yields in excited-state electron transfer reactions of 1,12-benzperylene in acetonitrile" @default.
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- W2056680443 doi "https://doi.org/10.1016/s0009-2614(97)01294-3" @default.
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