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• W2056695762 startingPage "201" @default.
• W2056695762 abstract "Chelating ligands based upon 8-(dimethylsilyl)quinoline have been synthesized and used to prepare complexes of Rh(III) and Ir(III) in which the ligand coordinates the metal through a combination of M-N and M-Si linkages. These types of complexes have been formed via oxidative addition of the Rh(I) or Ir(I) precursors across either an Si-H or Si-Si bond of the N,Si-chelating ligand, and both bis- and tris-chelated species have been characterized. We report here the first photophysical characterizations of this new class of complexes. Their photophysical properties suggest that substantial modifications, relative to ortho-metalated species, occur as a result of the highly covalent nature of M-Si bonds as compared to M-C bonds." @default.
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• W2056695762 date "1991-12-01" @default.
• W2056695762 modified "2023-09-23" @default.
• W2056695762 title "A new class of metal-silicon bonded complexes: 8-(dimethylsilyl) quinoline derivatives of rhodium and iridium" @default.
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• W2056695762 doi "https://doi.org/10.1016/0010-8545(91)84025-z" @default.
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