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- W2056762283 abstract "The electron-stimulated desorption of metastable molecular nitrogen (N2*) from N2 condensed onto n-hexane spacer films deposited on Pt(111) is investigated as a function of electron-impact energy (5–25 eV), and thickness (1–20 monolayers) and deposition temperature (T=20–80 K) of the n-hexane layer. At low T, the N2* yield is found to be inversely proportional to the thickness of the amorphous n-hexane layer. This behavior is explained by the existence of a porous structure in the n-hexane film which efficiently absorbs N2. The metastable signal is also strongly dependent on the temperature of n-hexane deposition, which controls the morphology of the spacer from amorphous at low T to crystalline at T>70 K. Increasing the deposition temperature of n-hexane from 20 to 70 K results in an increase of the N2* signal due to the decrease of the pore volume. Formation of the n-hexane layers in the crystalline state at higher temperatures further inhibits N2 migration into the spacer which results in further increases in the magnitude of the N2* desorption signal." @default.
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- W2056762283 date "1999-04-22" @default.
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- W2056762283 title "Sample morphology and porosity in electron stimulated desorption: N2* from N2 adsorbed onto glassy and crystalline n-hexane" @default.
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- W2056762283 doi "https://doi.org/10.1063/1.478714" @default.
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