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- W2056772633 abstract "Semi-empirical SCFMO calculations were made of the energies, and geometric and electronics structures of a range of radical ions of type MR3± and M2R6± where M = Al, Si or P, and R = H or CH3. In each of the MH3 radicals, methylation effects an increase in the HMH angle: the structure of Al2Me6−, formed by γ-irradiation of Al2Me6, is found to have Cs symmetry and to resemble a weak complex of AlMe2 and AlMe4−. Possible identities for the radical, other than AlH3−, formed on γ-irradiation of LiAlH4 are suggested, and a considerable number of plausible identities are firmly ruled out." @default.
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- W2056772633 date "1985-02-01" @default.
- W2056772633 modified "2023-09-26" @default.
- W2056772633 title "Radical ions derived from hydrides and methyls of aluminum, silicon and phosphorus: A semi-empirical SCFMO study" @default.
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- W2056772633 doi "https://doi.org/10.1016/s0020-1693(00)86580-9" @default.
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