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- W2056776413 abstract "The effect of tetra- n -alkylammonium bromides, R 4 NBr (R=CH 3 , C 2 H 5 , C 4 H 9 ) on the densities, ρ , of glycine, l -alanine and glycylglycine are reported at T =298.15 K. The apparent molar volumes of amino acids in aqueous tetra- n -alkylammonium salts, φ VAJW , and of tetra- n -alkylammonium bromides in aqueous amino acids and peptide, φ VJAW , are calculated from the measured densities. Both φ VAJW and φ VJAW have been analysed accurately using a simple equation. Positive transfer volumes are observed for glycine, l -alanine and glycylglycine in the presence of R 4 NBr. Tetra- n -butylammonium bromide shows almost double increase in the transfer volumes of amino acids or peptide than tetramethyl- or tetraethylammonium bromides. Negative transfer volumes for the tetra- n -alkylammonium bromide salts are noted in aqueous amino acids or peptide due to large tetra- n -alkylammonium cation undergoing hydrophobic hydration." @default.
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- W2056776413 date "2004-01-01" @default.
- W2056776413 modified "2023-09-27" @default.
- W2056776413 title "Effect of tetra-n-alkylammonium bromides on the volumetric properties of glycine, l-alanine and glycylglycine at T=298.15 K" @default.
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- W2056776413 doi "https://doi.org/10.1016/j.jct.2003.09.008" @default.
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