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- W2056831334 abstract "The kinetics of cyanide addition to the water soluble oxybridged iron dimer of tetra (p-sulophenyl) porphin indicate that HCN is the reactant. The rate law is of the form: Rate = (3·8 ± 0·2) × 104 (Fe dimer) (HCN)/(1 + (3·1 ± 0·3) × 1010 (H+)) at 25°, μ = 0·7 (NaNO3). The cyano iron dimer dissociates into dicyano iron monomers by two pathways, one first order in (H+), and one proportional to (H+)(CN−)2. The mechanism of this dimer reaction is compared to iron porphyrin monomer systems." @default.
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- W2056831334 date "1975-02-01" @default.
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- W2056831334 title "Metal-porphyrin interactions—V kinetics of cyanide addition to a water soluble iron porphyrin dimer[1]" @default.
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- W2056831334 doi "https://doi.org/10.1016/0022-1902(75)80372-1" @default.
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