Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056854668> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2056854668 endingPage "2124" @default.
- W2056854668 startingPage "2119" @default.
- W2056854668 abstract "The tripod ligand HC(PPh2)3 reacts with Mo(CO)3(CH3CN)3 yielding Mo(CO)3(CH3CN)(HC(PPh2)3). Reaction of this Mo0 complex with [Rh(CO)2Cl]2 gives unexpectedly the tetranuclear species [Rh2(CO)(HC(PPh2)3)]2(μ-Cl)+3 (3) which crystallizes as the Rh(CO)2Cl−2 salt (3a). This complex crystallizes in the monoclinic space group P21/c with Z = 4, with all dimensions a = 19.685(3), b = 19.524(3), c = 22.657(4) Å, and β = 96.96(2)°. A direct route to the PF−6 salt of 3 (3b) is also presented. The 31P NMR data show 3a and 3b to be identical and that the tetranuclear structure is retained in solution, i.e. two units of binuclear RhI species bridged by three chlorine atoms. In each binuclear unit, the tripod ligand spans two RhI which are linked directly by a metal-metal bond (RhRh = 2.696 Å)." @default.
- W2056854668 created "2016-06-24" @default.
- W2056854668 creator A5009085745 @default.
- W2056854668 creator A5039178219 @default.
- W2056854668 creator A5051505068 @default.
- W2056854668 creator A5063833209 @default.
- W2056854668 creator A5071337263 @default.
- W2056854668 date "1989-01-01" @default.
- W2056854668 modified "2023-10-18" @default.
- W2056854668 title "Synthesis and structure of a triply-chloro-bridged dimer of a homobinuclear RhI complex: [{Rh2(CO)(HC(PPh2)3)}2(μ-Cl)3]+[Rh(CO)2Cl2]−" @default.
- W2056854668 cites W1965985664 @default.
- W2056854668 cites W1970626388 @default.
- W2056854668 cites W2022620351 @default.
- W2056854668 cites W2061291949 @default.
- W2056854668 cites W2093213301 @default.
- W2056854668 cites W426754412 @default.
- W2056854668 cites W625827176 @default.
- W2056854668 cites W2298590419 @default.
- W2056854668 doi "https://doi.org/10.1016/s0277-5387(00)80345-9" @default.
- W2056854668 hasPublicationYear "1989" @default.
- W2056854668 type Work @default.
- W2056854668 sameAs 2056854668 @default.
- W2056854668 citedByCount "2" @default.
- W2056854668 crossrefType "journal-article" @default.
- W2056854668 hasAuthorship W2056854668A5009085745 @default.
- W2056854668 hasAuthorship W2056854668A5039178219 @default.
- W2056854668 hasAuthorship W2056854668A5051505068 @default.
- W2056854668 hasAuthorship W2056854668A5063833209 @default.
- W2056854668 hasAuthorship W2056854668A5071337263 @default.
- W2056854668 hasConcept C115624301 @default.
- W2056854668 hasConcept C116569031 @default.
- W2056854668 hasConcept C120665830 @default.
- W2056854668 hasConcept C121332964 @default.
- W2056854668 hasConcept C130614165 @default.
- W2056854668 hasConcept C155647269 @default.
- W2056854668 hasConcept C161790260 @default.
- W2056854668 hasConcept C170493617 @default.
- W2056854668 hasConcept C178790620 @default.
- W2056854668 hasConcept C185592680 @default.
- W2056854668 hasConcept C2779546866 @default.
- W2056854668 hasConcept C2993530813 @default.
- W2056854668 hasConcept C521398313 @default.
- W2056854668 hasConcept C544153396 @default.
- W2056854668 hasConcept C55493867 @default.
- W2056854668 hasConcept C61276311 @default.
- W2056854668 hasConcept C71240020 @default.
- W2056854668 hasConcept C8010536 @default.
- W2056854668 hasConceptScore W2056854668C115624301 @default.
- W2056854668 hasConceptScore W2056854668C116569031 @default.
- W2056854668 hasConceptScore W2056854668C120665830 @default.
- W2056854668 hasConceptScore W2056854668C121332964 @default.
- W2056854668 hasConceptScore W2056854668C130614165 @default.
- W2056854668 hasConceptScore W2056854668C155647269 @default.
- W2056854668 hasConceptScore W2056854668C161790260 @default.
- W2056854668 hasConceptScore W2056854668C170493617 @default.
- W2056854668 hasConceptScore W2056854668C178790620 @default.
- W2056854668 hasConceptScore W2056854668C185592680 @default.
- W2056854668 hasConceptScore W2056854668C2779546866 @default.
- W2056854668 hasConceptScore W2056854668C2993530813 @default.
- W2056854668 hasConceptScore W2056854668C521398313 @default.
- W2056854668 hasConceptScore W2056854668C544153396 @default.
- W2056854668 hasConceptScore W2056854668C55493867 @default.
- W2056854668 hasConceptScore W2056854668C61276311 @default.
- W2056854668 hasConceptScore W2056854668C71240020 @default.
- W2056854668 hasConceptScore W2056854668C8010536 @default.
- W2056854668 hasIssue "17" @default.
- W2056854668 hasLocation W20568546681 @default.
- W2056854668 hasOpenAccess W2056854668 @default.
- W2056854668 hasPrimaryLocation W20568546681 @default.
- W2056854668 hasRelatedWork W1005319209 @default.
- W2056854668 hasRelatedWork W1976229181 @default.
- W2056854668 hasRelatedWork W1991883810 @default.
- W2056854668 hasRelatedWork W1993586508 @default.
- W2056854668 hasRelatedWork W2023243933 @default.
- W2056854668 hasRelatedWork W2088714404 @default.
- W2056854668 hasRelatedWork W2353059933 @default.
- W2056854668 hasRelatedWork W2391680976 @default.
- W2056854668 hasRelatedWork W2989615473 @default.
- W2056854668 hasRelatedWork W3142280136 @default.
- W2056854668 hasVolume "8" @default.
- W2056854668 isParatext "false" @default.
- W2056854668 isRetracted "false" @default.
- W2056854668 magId "2056854668" @default.
- W2056854668 workType "article" @default.