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- W2056877029 abstract "Ultrathin films of vanadium oxides (0.9–2.6 ML) grown on Ni(110) surface have been studied using XPS and LEED. The 0.9 ML vanadium oxide prepared by exposure of deposited vanadium atoms to 1×10−5 Pa O2 at 310 K and then at 523 K, gives VO(111)-like oxide, as indicated by the LEED pattern. The 1.7 ML oxide shows a VO(111)–(2×2) structure. Preparation of the oxide film at 623 K under 5×10−4 Pa O2 without a preoxidation at 310 K, leads to an LEED pattern with only streaks and to formation of ≈1.0 ML nickel oxide under the vanadium oxide. A single Ni 2p3/2 peak of the nickel oxide shows a large chemical shift of ≈3.0 eV. The oxide film gives a streaky (1×6) pattern by heating at 773 K under 5×10−4 Pa O2 and a VO(111)–(2×2) pattern by heating at 673 K in vacuo. The reaction of the VO(111)–(2×2) surface with sodium atoms results in the formation of an oxide containing Na+ and V5+ after heating at 473 K under 1×10−5 Pa O2. © 1997 Elsevier Science B.V." @default.
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- W2056877029 date "1997-07-01" @default.
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- W2056877029 title "The structures and chemical states of ultrathin vanadium oxides on Ni(110) surface studied by LEED and XPS" @default.
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- W2056877029 doi "https://doi.org/10.1016/s0368-2048(96)03093-9" @default.
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