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• W2056927861 abstract "Abstract Mass fluxes of ZnSe by physical vapor transport (PVT) were measured in the temperature range of 1050–1140°C using an in situ dynamic technique. The starting materials were heat treated by a hydrogen reduction process followed by the dynamic bake-out method. The amount and composition of the residual gas inside the experimental ampoules were measured after the transport experiments using a total-pressure gauge. The total residual gas pressures measured were about one order of magnitude lower than the values reported on similar processed ZnSe ampoules which were not treated with a hydrogen reduction process. As a result of the reduction in the residual gas pressure, the measured fluxes were 3–7 times higher than previously reported and correspond to a growth rate higher than 10 mm/day at 1120°C. The simultaneous measurements of partial pressures of transport species and the mass fluxes were also performed on a ZnSe optical ampoule. The partial pressures of Zn and Se 2 were obtained by measuring the optical densities of the vapor at the wavelengths of 2138, 3405, 3508, 3613, and 3792 A. For the first time, the experimentally obtained mass fluxes were compared with those calculated, without any adjustable parameters, from a one-dimensional diffusion model which uses all the measured parameters (thermal field, partial pressures of transport species, and residual gas) as inputs, and good agreement was observed." @default.
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• W2056927861 date "1996-09-01" @default.
• W2056927861 modified "2023-09-26" @default.
• W2056927861 title "Mass flux and partial pressures of ZnSe by physical vapor transport" @default.
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• W2056927861 doi "https://doi.org/10.1016/0022-0248(95)00509-9" @default.
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