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- W2056943918 abstract "A universal pattern emerging from the analysis of the distribution of relaxation times in the isotropic phase of liquid crystalline $n$-alkylcyanobiphenyls $(ntext{CB})$ from 4CB to 14CB is presented. The increase of the length of $ntext{CB}$ molecules causes the high-frequency (short-time) branch of the primary relaxation loss curve to approach the form $ensuremath{epsilon}(f>{f}_{peak})ensuremath{sim}{ensuremath{omega}}^{ensuremath{-}n}$, with $nensuremath{rightarrow}1/2$ in frequency $(ensuremath{omega}=2ensuremath{pi}f)$ or $ensuremath{sim}sqrt{t}$ in time on cooling toward the isotropic-mesophase ``clearing'' phase-transition temperature $({T}^{C})$. Recently, such behavior was suggested as a hypothetical universal pattern for diverse glass forming organic liquids on approaching the glass temperature [A. I. Nielsen, T. Christensen, B. Jakobsen, K. Niss, N. B. Olsen, R. Richert, and J. C. Dyre, J. Chem. Phys. 130, 154508 (2009)]. The isotropic phase of rodlike liquid crystalline compounds is considered to be an important experimental model system for studying glassy dynamics since it constitutes a link with the model fluid of hard ellipsoids of revolution." @default.
- W2056943918 created "2016-06-24" @default.
- W2056943918 creator A5043587562 @default.
- W2056943918 date "2009-07-14" @default.
- W2056943918 modified "2023-09-27" @default.
- W2056943918 title "Universal pattern for the distribution of relaxation times in the isotropic phase of liquid crystalline<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>n</mml:mi></mml:math>-cyanobiphenyls" @default.
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- W2056943918 doi "https://doi.org/10.1103/physreve.80.011704" @default.
- W2056943918 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19658715" @default.
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