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- W2056958049 abstract "Abstract The complexes [Ni(eten) 3 ]X 2 ·H 2 O (eten = N -ethyl-1,2-ethanediamine; X = Cl, Br), [Ni(eten) 3 ]X 2 (X = BF 4 , NO 3 , 0.5SO 4 , 0.5SeO 4 ), [Ni(eten) 2 X 2 ·2H 2 O (X = Cl, Br) and [Ni(meen) 3 ]X 2 ·2H 2 O (meen = N -miethyl-1,2-ethanediamine; X = 0.5SO 4 , 0.5SeO 4 ) have been synthesized from solution and their thermal investigation carried out in the solid state. [Ni(eten) 3 ]Br 2 [Ni(eten) 2 X 2 ] (X = Cl, Br, 0.5SO 4 , 0.5SeO 4 ), [Ni(eten)Cl 2 ], Ni(eten) 0.5 Cl 2 and [Ni(meen) 2 X 2 ] (X = 0.5SO 4 , 0.5SeO 4 ) were isolated in the solid state from their corresponding parent complexes by a pyrolytic technique. Upon heating, [Ni(eten) 2 X 2 ] (X = Cl, Br) and [Ni(eten) 3 ](BF 4 ) 2 undergo endothermic, kinetically irreversible phase transition, whereas [Ni(meen) 3 ]SeO 4 undergoes exothermic irreversible phase transition. The phase transition phenomena are assumed to be due to conformational changes in the diamine chelate rings. All the complexes except Ni(eten) 0.5 Cl 2 have octahedral geometry. Ni(eten) 0.5 Cl 2 has an unusually high magnetic moment." @default.
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- W2056958049 date "1989-12-01" @default.
- W2056958049 modified "2023-09-27" @default.
- W2056958049 title "Solid state thermal studies of nickel(II) diamine complexes" @default.
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- W2056958049 doi "https://doi.org/10.1016/0040-6031(89)87155-2" @default.
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