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• W2056965763 abstract "To improve the activity of Au/TiO2 catalysts toward hydrogenation without decreasing chemoselectivity, a number of isolated and supported Au, Pt, and Au−Pt nanoparticles have been investigated by means of density functional theory (DFT) calculations. H2 dissociation on Pt and Au−Pt nanoparticles is considerably faster than that on Au, because H2 adsorption on Pt atoms is dissociative and no activation barriers are involved. The high chemoselectivity of Au/TiO2 catalysts does not exist in Pt/TiO2 catalysts no matter how small the Pt particles are, but can be preserved in Au−Pt/TiO2 catalysts if the Au/Pt ratio is high enough as to keep Pt atoms isolated and not at the active metal−support interface." @default.
• W2056965763 created "2016-06-24" @default.
• W2056965763 creator A5000454699 @default.
• W2056965763 creator A5066479662 @default.
• W2056965763 date "2010-06-28" @default.
• W2056965763 modified "2023-09-25" @default.
• W2056965763 title "Origin of the Different Activity and Selectivity toward Hydrogenation of Single Metal Au and Pt on TiO₂ and Bimetallic Au−Pt/TiO₂ Catalysts" @default.
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• W2056965763 doi "https://doi.org/10.1021/la101752a" @default.
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• W2056965763 hasPublicationYear "2010" @default.
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