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- W2056977422 abstract "Abstract The new compound Yb 2+3— x Pd 12—3+ x P 7 x = 0.40(4)) was synthesized by sintering of a mixture of elemental components at 1100 °C with subsequent annealing at 800 °C. The crystal structure of Yb 2+3— x Pd 12—3+ x P 7 was solved and refined from X‐ray single‐crystal diffraction data: space group P 6¯, a = 10.0094(4)Å, c = 3.9543(2)Å, Z = 1; R(F) = 0.022 for 814 observed unique reflections and 38 refined parameters. The atomic arrangement reproduces a structure motif of the hexagonal Zr 2 Fe 12 P 7 type in which one of the transition metal positions is substituted predominantly by ytterbium (Yb : Pd = 0.86(1) : 0.14). The ytterbium atoms are embedded in the 3D polyanion formed by palladium and phosphorus atoms. Two different environments for ytterbium atoms are present in the structure. Magnetic susceptibility measurements and XAS spectroscopy at the Yb L III edge show the presence of ytterbium in two electronic configurations, 4ƒ 13 and 4ƒ 14 . The following model was derived. Ytterbium atoms in the 3 k site are in the 4ƒ 13 state, the two remaining positions contain ytterbium in intermediate‐valence states, giving totally 79 % ytterbium in the 4ƒ 13 electronic configuration." @default.
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- W2056977422 date "2004-06-15" @default.
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- W2056977422 title "Yb2+3—xPd12—3+xP7 (x = 0.40): Different Ytterbium Species in a Substituted Structural Motif of the Zr2Fe12P7 Type" @default.
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- W2056977422 doi "https://doi.org/10.1002/zaac.200400113" @default.
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