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- W2056990822 endingPage "8658" @default.
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- W2056990822 abstract "Cyclopropanation reactions of 6-deoxyhex-5-enopyranosides by methylene-zinc-iodide complex, dichlorocarbene, and rhodium ethoxycarbonyl complex addition afford optimum yields of the corresponding spirocyclopropanes. Surprisingly, a stereospecific spirocyclopropane derivative with the two halogens on the upper face of the 4-hydroxy substituent is obtained. To get more insight on the dichlorocarbene cyclopropanation process a computational study, based on DFT quantomechanic calculation was conducted." @default.
- W2056990822 created "2016-06-24" @default.
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- W2056990822 date "2008-09-01" @default.
- W2056990822 modified "2023-10-17" @default.
- W2056990822 title "Cyclopropanation of 5-methylene galactopyranosides by dihalo-, ethoxycarbonyl-, and unsubstituted carbenes" @default.
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- W2056990822 doi "https://doi.org/10.1016/j.tet.2008.07.013" @default.
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