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- W2057071305 abstract "The acidity constants of the conjugate acids of 19 N-bases of various structural types were measured at 298.15 K in anhydrous cyclohexanone, acetone, and butan-2-one as solvents; according to the reaction: BH+ +S=SH+ +B. A glass electrode was shown to be responsive to hydrogen ion in those solvents. The pKa values of most of the protonated N-bases studied in ketones as solvents are from 1 to 4.5 times greater than the corresponding values in water. Some tendency to form homoconjugated complexes BHB+ have been observed according to the reaction: BH+ + B=BHB+." @default.
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- W2057071305 date "1991-02-01" @default.
- W2057071305 modified "2023-09-27" @default.
- W2057071305 title "Acidity constants of 19 protonated N-bases in cyclohexanone, acetone, and butan-2-one" @default.
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- W2057071305 doi "https://doi.org/10.1016/s0021-9614(05)80289-7" @default.
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