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- W2057078353 abstract "The energy distribution of various ions formed by field ionization on a tip has been investigated by a retarding potential technique. The field appearance potential (APf) for singly- and doubly-charged molecular ions and ion clusters are shown to be equal to the energies of their formation. This has made it possible to measure the ionization potentials of a number of molecules and radicals, to determine the bond energy in the H3O+ −H2O ion (1.60±0.1 eV), the proton affinity of the formic acid molecule (8.10±0.1 eV) and the hydrogen atom affinity of the NH4+ ion (>4 eV). It is also shown that the energy distributions of different fragment ions are greatly dependent upon the types of bonds broken and structures of fragments." @default.
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- W2057078353 date "1974-04-01" @default.
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- W2057078353 title "Analysis of field ion energies in a mass spectrometer" @default.
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- W2057078353 doi "https://doi.org/10.1016/0020-7381(74)83011-1" @default.
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