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- W2057109062 abstract "Three types of hybrid transition-alkali metal complexes, [MK2(pdc)2(H2O)7]n (H2pdc = 2,6-pyridinedicarboxylic acid, or so-called dipicolinic acid, M = Mn (1), Co (2), Zn (3), Mn0.5Co0.5 (4)), {[Na2(H2O)8(CH3OH)0.5][Mn2Na2(pdc)4(H2O)8]·0.25CH3OH·2H2O}n (5) and [Ni(H2O)6][Ni2K2(pdc)4(H2pdc)2(H2O)2]·2H2O (6) were self-assembled from a reaction system containing a divalent transition metal, alkali metal and H2pdc, and were isolated under different crystallization conditions. In all complexes, [M(pdc)2]2− units were included as independent components to connect to the alkali metal chains or pdc units. Alkali metal ions act as templates for inducing the organization of the [M(pdc)2]2− components into respective special architectures in different fashions. Complexes 1–4 are isostructural with the same space group and similar cell parameters, in which the [M(pdc)2]2− units are bonded to the water-bridged K chains forming neutral 2D lamellar-like polymers, while 5 contains water-bridged Na chains correlated to Mn2..." @default.
- W2057109062 created "2016-06-24" @default.
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- W2057109062 date "2003-02-01" @default.
- W2057109062 modified "2023-09-23" @default.
- W2057109062 title "Syntheses and Structures of Three Types of Hybrid Metal Dipicolinato Complexes Induced by Alkali Metal Ion and the Semiconductor Character" @default.
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- W2057109062 doi "https://doi.org/10.1246/bcsj.76.301" @default.
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