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- W2057114597 abstract "The reactions of the Schiff-base N,N-ethylenebis-(isonitrosoacetylacetoneimine), (H2L), with Ni(II) acetate led to the formation of the yellow-orange complex LNi (I) in water and the red complex LNi (II) in ethanol. Both oximato groups in I are coordinated to the metal through the oximino-oxygen whereas in II one group is similarly coordinated while the other is coordinated through the oximino-nitrogen. Complex I was converted to complex II by boiling in chloroform and the conversion was reversed by reacting complex II with either piperidine or ethylenediamine. H2L neutralized by ammonia reacted with Ni(II) chloride (1:1) and the complex formed was characterized as the red square planar bis-(4-iminopentane-2,3-dione 3-oximato)Ni(II);(III). This trans complex reacted with piperidine (1:4) to produce its cis configuration (IV). Complex III reacted with ethylenediamine (2:1) and 1,3-diaminopropane (1:1) to produce complexes II and V respectively of the identical structure. Attempted similar reaction (1:1) with either 1,4-diaminobutane or 1,5-diaminopentane led to the formation of the binuclear complexes VI and VII in which two molecules of complex III are linked together by -(CH2)4- and -(CH2)5-Moieties respectively. The suggested structures of the square planar Ni(II) complexes are based on analytical, spectral and magnetic moment evidence." @default.
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- W2057114597 date "1985-01-01" @default.
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- W2057114597 title "Linkage isomerism of the oximato group: The characterization of some mono- and binuclear square planar nickel(II) complexes of vicinal oxime-imine ligands" @default.
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- W2057114597 doi "https://doi.org/10.1016/s0277-5387(00)84123-6" @default.
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