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- W2057121993 abstract "Abstract We report the first successful allylation of aromatic esters by allyltrimethylsilane. The reaction is mediated by 0.3–1.0 equiv. of titanium tetrachloride (TiCl 4 ) at room temperature and leads in a multi‐step, one‐pot reaction to quaternary triallylmethane derivatives 5 . The most efficient ester possessed two ortho ‐methoxy substituents on the phenol ring. Molecular modelling revealed the ability of this compound to form a bidentate titanium complex, thus improving the steric accessibility of the ester carbonyl to nucleophilic attack. magnified image" @default.
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- W2057121993 date "2014-06-24" @default.
- W2057121993 modified "2023-09-27" @default.
- W2057121993 title "The First Allylation of Esters by an Allylsilane: One-Pot Domino Synthesis of Triallylmethane Derivatives" @default.
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- W2057121993 doi "https://doi.org/10.1002/adsc.201400296" @default.
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