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- W2057150147 abstract "We report on the light induced spin crossover dynamics of [Fe(2 CH3-phen)3]2+ complex in solution. The excitation of the complex by pulses centered at λ = 500 nm along the metal to ligand charge transfer absorption band indicates a selective excitation of the LS state. The excitation of the complex by pulses centered at λ = 330 nm or λ = 335 nm reveals an increase of the LS state population and a photo-bleaching of the HS state population that is associated to a transient photo-dissociation. A method that makes it possible to deduce the kinetics of both the HS → LS state and LS → HS state is proposed." @default.
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- W2057150147 date "2013-01-01" @default.
- W2057150147 modified "2023-10-17" @default.
- W2057150147 title "Transient absorption spectroscopy of the [Fe(2 CH3-phen)3]2+ complex: Study of the high spin↔low spin relaxation of an isolated iron(II) complex" @default.
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- W2057150147 doi "https://doi.org/10.1016/j.cplett.2012.11.034" @default.
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