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• W2057169320 abstract "The Knight shift ( K H ) and the spin-lattice relaxation time T 1 , of protons have been measured in vanadium-hydrogen alloys (VH x ) with hydrogen concentration x =0.042∼0.736, at temperatures between 100° and 200°C. The resolution of ±1 ppm in the shift was attained by using a high-resolution spectrometer, and the effect of demagnetizing field was isolated by using a single sheet of foil as a specimen. This allowed the simultaneous determination of K H and the bulk magnetic susceptibility. K H measured relative to bare protons was found to be negative and change little with hydrogen concentration. No temperature dependence of the shift was observed, even across the phase transition. These results are interpreted in terms of a contact interaction with the uniform spin-polarization in the interstitial region and some additional contributions from H-induced states. An evidence for the electron-electron interaction in VH x is derived from comparison of K H and T 1 ." @default.
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• W2057169320 date "1977-01-01" @default.
• W2057169320 modified "2023-10-17" @default.
• W2057169320 title "Local Electronic Environment of Protons in VH_<i>x</i> Alloys: Knight Shift and T₁ of Proton NMR" @default.
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• W2057169320 doi "https://doi.org/10.1143/jpsj.42.119" @default.
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