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- W2057172314 abstract "The ring-opening polymerization of ε-caprolactone (ε-CL) and rac-lactide (rac-LA) under solvent-free conditions and using 1-n-butyl-3-methylimidazolium-2-carboxylate (BMIM-2-CO2) as precatalyst is described. Linear and star-branched polyesters were synthesized by successive use of benzyl alcohol, ethylene glycol, glycerol and pentaerythritol as initiator alcohols, and the products were fully characterized by (1)H and (13)C{(1)H} NMR spectroscopy, gel permeation chromatography (GPC), and differential scanning calorimetry (DSC). BMIM-2-CO2 acts as an N-heterocyclic carbene precursor, resulting from in situ decarboxylation, either by heating under vacuo (method A) or by addition of NaBPh4 (method B). Possible catalytic and deactivation mechanisms are proposed." @default.
- W2057172314 created "2016-06-24" @default.
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- W2057172314 date "2013-04-03" @default.
- W2057172314 modified "2023-10-06" @default.
- W2057172314 title "1-<i>n</i>-Butyl-3-methylimidazolium-2-carboxylate: a versatile precatalyst for the ring-opening polymerization of ε-caprolactone and <i>rac</i>-lactide under solvent-free conditions" @default.
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- W2057172314 doi "https://doi.org/10.3762/bjoc.9.73" @default.
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