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• W2057187410 startingPage "1395" @default.
• W2057187410 abstract "The inherently chiral tetrabenzoxazine resorcarene derivative 1 shows characteristic plateau-formation during enantioselective HPLC separation on the chiral stationary phase Chiralpak AD. By computer assisted peak form analysis of the elution profiles, obtained from temperature dependent dynamic HPLC (DHPLC) experiments, with ChromWin, the enantiomerization barrier ΔG#(298 K)=92±2 kJ mol−1 and the activation parameters ΔH#=53.0±1.8 kJ mol−1 and ΔS#=−131±14 J (K mol)−1 were determined." @default.
• W2057187410 created "2016-06-24" @default.
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• W2057187410 date "2001-06-01" @default.
• W2057187410 modified "2023-10-05" @default.
• W2057187410 title "Enantiomerization of an inherently chiral resorcarene derivative: determination of the interconversion barrier by computer simulation of the dynamic HPLC experiment" @default.
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• W2057187410 doi "https://doi.org/10.1016/s0957-4166(01)00246-4" @default.
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