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- W2057233876 abstract "A somewhat speculative reaction scheme is advanced to account for the existence of H3O+ and H5O2+ ions in the mesosphere. The precursor for these ions is shown to be NO+ rather than O2+ on the basis of the reaction H + (NO+·H2O) → H3O+ + NO proposed by Burke(1970). The rapid decline in the observed H3O+ and H5O2+ ion concentrations above 80 km is attributed to the reaction of atomic oxygen with constituents in the reaction chain. The use of observed NO distributions in the mesosphere is shown to result in excessively high electron concentrations, unless it is assumed that NO+ cluster ions with very high dissociative recombination rates are formed. Fairly good agreement between the calculated ion and electron densities and observation is obtained, but a substantial amount of laboratory work is required to verify the proposed reaction scheme." @default.
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- W2057233876 date "1971-06-01" @default.
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- W2057233876 title "Cluster ions and nitric oxide in the D-region" @default.
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- W2057233876 doi "https://doi.org/10.1016/0021-9169(71)90092-4" @default.
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