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- W2057237869 abstract "We show that 5'-Gs in 5'-GG-3' duplex DNA dinucleotide steps are preferentially oxidized by the trioxatriangulenium ion (TOTA( plus sign in circle )) upon photo-activation, an oxidation pattern characteristic of guanine radical cation formation. Some photo-oxidation of the 3'G in 5'GG3' steps and of isolated guanines is also observed but reactions carried out in D(2)O reveal only a minor increase in oxidation damage at these sites, indicating that electron transfer is the primary mechanism of guanine oxidation." @default.
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- W2057237869 date "2003-04-01" @default.
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- W2057237869 title "Photo-oxidation of duplex DNA with the stable trioxatriangulenium ion" @default.
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- W2057237869 doi "https://doi.org/10.1016/s0960-894x(03)00121-5" @default.
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