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- W2057277112 abstract "The synthesis of a new deep cavitand partially bridged via disulfide bonds is described. Its thermodynamic and kinetic complexation parameters are compared with those of an unbridged analogue. The disulfide bridges cause deviations in ΔH and ΔS but result in only small differences in ΔG of complexation. The bridges increase the activation barrier for guest dissociation and lead to complexes with enhanced kinetic stability." @default.
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- W2057277112 date "2010-10-05" @default.
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- W2057277112 title "Guest Recognition in a Partially Bridged Deep Cavitand" @default.
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- W2057277112 doi "https://doi.org/10.1021/ol101980f" @default.
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