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- W2057291735 abstract "A novel three-dimensional coordination polymer, {[Pb(C 14 H 8 N 2 O 4 )(H 2 O)]·0.5C 12 H 10 N 2 } n , has been synthesized by hydrothermal reaction of Pb(OAc) 2 ·3H 2 O (OAc is acetate), 2,2′-(diazene-1,2-diyl)dibenzoic acid (H 2 L ) and 1,2-bis(pyridin-4-yl)ethylene (bpe). The asymmetric unit contains a crystallographically independent Pb II cation, one L 2− ligand, an aqua ligand and half a bpe molecule. Each Pb II centre is seven-coordinated by six O atoms of bridging–chelating carboxylate groups from L 2− ligands and by one O atom from a coordinated water molecule. The Pb II cations are bridged by L 2− ligands, forming [PbO 2 ] n chains along the a axis. These chains are further connected by L 2− ligands along the b and c axes to give a three-dimensional framework with a 4 12 6 3 topology. The channel voids are occupied by bpe molecules." @default.
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- W2057291735 date "2014-09-04" @default.
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- W2057291735 title "The three-dimensional coordination polymer poly[[aqua[μ<sub>4</sub>-2,2′-(diazene-1,2-diyl)dibenzoato]lead(II)] 1,2-bis(pyridin-4-yl)ethylene hemisolvate]" @default.
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- W2057291735 doi "https://doi.org/10.1107/s2053229614017951" @default.
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