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• W2057306768 endingPage "240" @default.
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• W2057306768 abstract "• Two molecular solids containing [Co(NCS) 4 ] 2− dianion were prepared and characterized. • There are C H⋯Cl, C H⋯S, C H⋯S, C H⋯Co, p⋯π, C H⋯π and interactions in 1 and 2 . • Two molecular solids show a broad fluorescence emission at room temperature. • Two molecular solids show weak antiferromagnetic coupling behavior. Two new organic–inorganic molecular solids of tetra(isothiocyanate)cobalt(II) dianion and meta-substituted benzyl triphenylphosphinium, [2ClBzTPP] 2 [Co(NCS) 4 ] ( 1 ) and [4ClBzTPP] 2 [Co(NCS) 4 ] ( 2 ) ([2ClBzTPP] + = 1-(2′-chlorobenzyltriphenylphosphonium) and [4ClBzTPP] + = 1-(4′-chlorobenzyltriphenylphosphonium), were prepared and characterized by elemental analysis, FT-IR, UV–vis spectra, ESI-MS and single crystal X-ray diffraction method. Both 1 and 2 crystallize in monoclinic, and the Co(II) ion of the [Co(NCS) 4 ] 2− anion shows a distorted tetrahedral coordination geometry. The C H⋯Cl, C H⋯S hydrogen bonds were found in 1 while C H⋯S, C H⋯Co, p⋯π, C H⋯π interactions were found in 2 consolidating the stacking of the crystal. Magnetic susceptibility measurement in the temperature range 2–300 K shows that 1 and 2 exhibit a weak antiferromagnetic coupling behavior. Upon excitation at 268 nm, two molecular solids show the luminescent emission peak in the UV-light region in the solid state at room temperature." @default.
• W2057306768 created "2016-06-24" @default.
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• W2057306768 date "2015-01-01" @default.
• W2057306768 modified "2023-09-29" @default.
• W2057306768 title "Syntheses, crystal structures, weak interaction, magnetic and luminescent properties of two new organic–inorganic molecular solids with substituted chlorobenzyl triphenylphosphinium and tetra(isothiocyanate)cobalt(II) anion" @default.
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• W2057306768 doi "https://doi.org/10.1016/j.synthmet.2014.11.021" @default.
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