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- W2057324902 startingPage "3175" @default.
- W2057324902 abstract "Twelve new Co(III) complexes containing a hexaniobate ion Nb6O198− as a tridentate ligand were synthesized. The hexaniobato ligand coordinates facially, and the remaining three coordination sites are occupied by a tridentate amino carboxylato ligand or by a bidentate amino carboxylato ligand and NH3 or H2O. Two glycinato complexes, [Co(Nb6O19)(gly)(X)]6− (X=NH3 or H2O), were optically resolved, and a L-valinato complex [Co(Nb6O19)(L-val)(NH3)]6− was separated into two diastereomers. The structures of these complexes were determined from their visible and ultraviolet absorption, circular dichroism, and proton magnetic resonance spectra." @default.
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- W2057324902 date "1975-11-01" @default.
- W2057324902 modified "2023-10-14" @default.
- W2057324902 title "Preparation of the Co(III) Complexes with a Tridentate Hexaniobato and a Bi- or Tri-dentate Amino Carboxylato Ligand" @default.
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- W2057324902 doi "https://doi.org/10.1246/bcsj.48.3175" @default.
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