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- W2057330680 abstract "Variable temperature transmission electron microscopy of individual 5 nm Au nanoparticles shows a striking increase in the particle size on raising the temperature from room temperature to 500 °C in the presence of carbon from amorphous carbon support. Using the assembly of ordered graphene shells on the surface of individual nanoparticles at elevated temperatures—and the high pressures induced by such shells—as an experimental tool to study the origins of this swelling, we find that the volume increase is associated with the uptake of carbon to concentrations exceeding the bulk solubility by more than four orders of magnitude. The formation of stable metal–carbon nanostructures that have no bulk equivalent may have important implications on the functional properties of metal nanoparticles." @default.
- W2057330680 created "2016-06-24" @default.
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- W2057330680 date "2011-11-01" @default.
- W2057330680 modified "2023-10-03" @default.
- W2057330680 title "Giant carbon solubility in Au nanoparticles" @default.
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- W2057330680 doi "https://doi.org/10.1007/s10853-011-5663-9" @default.
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