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- W2057352014 abstract "A Fourier transform infrared (FTIR) difference spectrum upon photooxidation of the accessory chlorophyll (Chl z ) of photosystem II (PS II) was obtained at 210 K with Mn‐depleted PS II membranes in the presence of fericyanide and silicomolybdate. The observed Chl z + /Chl z spectrum showed two differential bands at 1747/1736 and 1714/1684 cm − . The former was assigned to the free carbomethoxy C = 0 and the latter to the keto C = 0 that is hydrogen‐bonded or in a highly polar environment. Also, the negative 1614 cm − band assignable to the macrocycle mode indicated 5‐coordination of the central Mg. The negative 1660 cm −1 band, possibly due to the strongly hydrogen‐bonded keto C = 0, may suggest oxidation of one more Chl z , although an alternative assignment, the amide I mode of proteins perturbed by Chl z oxidation, is also possible." @default.
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- W2057352014 date "1995-08-21" @default.
- W2057352014 modified "2023-09-25" @default.
- W2057352014 title "Molecular interactions of the redox-active accessory chlorophyll on the electron-donor side of photosystem II as studied by Fourier transform infrared spectroscopy" @default.
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- W2057352014 doi "https://doi.org/10.1016/0014-5793(95)00833-u" @default.
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