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• W2057369825 abstract "The hydrogen-bond lengths r(B…H-X) and r(B…D-X) have been redetermined on a consistent basis for the axially symmetric dimers B…HX, where B=N2, CO, PH3, HCN, CH3CN, NH3, or (CH3)3N and X=F, Cl or CN. For the series B…HF and B…HCl, the difference in the effective zero-point bond lengths δr=r(B…H-X)-r(B…D-X) is found to decrease as the hydrogen bond strength (kσ) increases. This behaviour is interpreted in terms of the effect of D substitution on the opposing contributions to the zero-point motion of the two modes (νS and νB) that involve large-amplitude displacements of the H atom." @default.
• W2057369825 created "2016-06-24" @default.
• W2057369825 creator A5009749885 @default.
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• W2057369825 date "1988-06-01" @default.
• W2057369825 modified "2023-09-23" @default.
• W2057369825 title "Systematic effect of d substitution on hydrogen-bond lengths in gas-phase dimers B…HX and a model for its interpretation" @default.
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• W2057369825 doi "https://doi.org/10.1016/0009-2614(88)85013-9" @default.
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