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- W2057399978 abstract "Polarized FT-IR spectra have been measured of a trace of water dissolved in a liquid crystal, 4′-n-octyl-4-cyanobiphenyl (8CB) which was highly oriented in a magnetic field. Two sharp bands with a shoulder observed in the OH stretching region, show apparent parallel dichroism with respect to the direction of the magnetic field. From infrared measurements of analogous systems consisting of water and benzonitrile and normal coordinate analysis, these spectral features are interpreted as the overlapping of water bands arising from two kinds of complexes, and 8CB—water—8CB complex (2:1 complex) and a water—8CB complex (1:1 complex) in which the water molecules are oriented following the orientation of 8CB through the hydrogen bondings between water and the CN group of 8CB." @default.
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- W2057399978 date "1984-04-01" @default.
- W2057399978 modified "2023-09-26" @default.
- W2057399978 title "Polarized FT—IR spectra of oriented water molecules in a liquid crystal" @default.
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- W2057399978 doi "https://doi.org/10.1016/0022-2860(84)80191-x" @default.
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