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- W2057404251 abstract "The arylation of sp3-hybridized C-H's bonds is a powerful strategy to build molecular complexity and diversity. A novel and efficient palladium-catalyzed direct sp3 C-H arylation of aryl and alkyl benzyl thioether derivatives with aryl bromides is reported. The reaction involves reversible deprotonation of the benzylic C-H's of the thioether with either LiN(SiMe3)2 or NaN(SiMe3)2 and subsequent cross-coupling to provide the functionalized products in up to 97% yield. A screen of 24 of the most successful ligands in cross-coupling chemistry led to the identification of NiXantPhos as the only viable ligand for this challenging coupling." @default.
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- W2057404251 date "2014-07-30" @default.
- W2057404251 modified "2023-10-01" @default.
- W2057404251 title "Palladium‐Catalyzed Direct α‐Arylation of Benzyl Thioethers with Aryl Bromides" @default.
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- W2057404251 doi "https://doi.org/10.1002/adsc.201400679" @default.
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